how to make calcium phosphate

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The ultrafilterable calcium equals the total of the ionized and complexed fractions. Like roasting coffee beans huh? You can see them here in the mayonnaise jar, which cost about $2.75 when it had mayo in it. -stephen. ( Log Out /  Change ), You are commenting using your Twitter account. The as-dried calcium phosphate powders were prepared in our laboratory. We couldn’t find that so we used the local brand vinegar we have here and still had good results. Don’t forget to follow me on Instagram ‘@marijuana.mama_420’ for more pictures of our grows! This makes it easier for the apple cider vinegar to break down the shells. Calcium hydroxide, or limewater, is made by mixing calcium oxide with water. Stir the eggshells frequently so the heat is evenly distributed and they don’t burn at the bottom. Required fields are marked *. Final photo of the sugar cane below. To get the calcium and calcium phosphate off the eggs and bones we use vinegar, which starts a reaction that releases the calcium, as well as carbon dioxide. w/o brown rice vinegar, grill or oven etc.) onto an LB plate (no antibiotics since these cells do not have a plasmid in them). Uroliths composed principally of calcium phosphate are uncommon in cats. This agent can be used as a countermeasure for exposure to strontium and radium radionuclides. To make sure you can safely take calcium phosphate, tell your doctor if you have any of these other conditions: a history of kidney stones; or. Below is Momodou pouring the vinegar over the eggshells and bones. A couple weeks later the trend looks the same – more vegetative growth in the WCA/WCP bed. Most people are left needing to buy a calcium supplement because finding a source of calcium for fertilizer is a little more difficult. Eggshells are all calcium but its locked up in the shell and unavailable to the plant. The more soluble superphosphate and triple superphosphate preparations are obtained by the treatment of calcium phosphate with sulfuric and phosphoric acid, respectively. **WARNING: the burnt egg shells have an unpleasant odor**. Calcium phosphate can be used as a supplement to increase your calcium and phosphorus intake, but it's also used as a food additive. It should be balanced with calcium in a 2:1 to 7:1 calcium-phosphorus ratio. Make sure you balance calcium and phosphate together for optimum health. Calcium phosphate uroliths have been found in association with primary hyperparathyroidism in humans and dogs, and this association has also been made in cats. Most of it, 99 percent, is in your bones and teeth. If you have the material sitting on the metal – even if you stir it constantly, they’ll scorch. You can see the bubbles from the CO2 being released. Thanks Stephen. a parathyroid gland disorder. ( Log Out /  In Korean natural farming, one of the most important organic and natural farming inputs is making calphos or calcium phosphate out of egg shells which you can find present in any kitchen big or small that you have at home. PLS make CaO by calcining CaCO3 aT 1273k. We didn’t have a grill or oven so Momodou improvised with some old corrugate roofing. We got our eggshells from a nice man named Mr. Jallow, he cooks breakfast here in Farafenni. Food-grade phosphoric acid is made from phosphate rocks, which are mined, refined and purified. Mix them up as they cook and try to get them to a light brown, again trying not to burn them black. It finds its application in food processing and preservation. If you want to eyeball it and leave the scale alone you can fill a jar 2/3 full with vinegar and then add eggshells till the jar is full. And now we can take a look at our groundnut beds. Your email address will not be published. Hey – to toast up those things I’d suggest using a perforated drum like a coffee roaster or bingo machine (or make one out of a tube, pot, or can) anything that can be rotated. It’s essentially the same process as WCA, but you use animal bones that have phosphorous in them. If the bubbles are still there, add some more cooked eggshells or bones and let it sit for another day or two. The complexed calcium is bound to molecules such as phosphate and citrate. Phosphoric acid and Calcium are good for plant cultivation. It's also used to help blend oil- and water-based ingredients, prevent caking, retain moisture, regulate acidity and treat flour. Streak out frozen glycerol stock of bacterial cells (Top10, DH5α, etc.) Water-soluble Calcium (WCA) is first. You can see below that there’s a big difference between these two beds. The History of the Civil War, penguin classic version. Heat the egg shells in the frying pan on medium heat until most of the shell pieces turn brown, even black with a little white. They look like a white powder and have no smell . If you consume eggs, or raise chickens, then making your own water soluble calcium at home is super easy. Be careful with the vinegar, something like that could really jinx your ph levels pretty easily IMO. The bed on the right in the photo below received WCA/WCP treatments. Put the chunks of bone over the fire and grill them. Stir vigorously while pouring seltzer over top. To create your own DIY CalMag+, simply add 1 Tbsp Calcium phosphate & 1 Tbsp of either Molasses or Epsom salt to a gallon of water. After the WCP, use WCA when the plants start to flower and fruit. Alessandro. We called it ‘cane of sweet’ to try to keep its identity hidden, as a way to prevent theft. As far as natural farming soil amendments go, WCA/WCP are simple and can be made very quickly and inexpensively with limited materials. Here is my counterpart breaking them up into smaller pieces. Talk to your doctor before taking calcium phosphate if you are breast-feeding a baby. Creating Calcium Phosphate. Calcium phosphate refers to numerous materials consisting of calcium ions (Ca 2+) together with orthophosphates (PO 43−), metaphosphates or pyrophosphates (P 2 O … Each supplement has largely the same effect on the body. The water-soluble calcium (WCA) is sprayed on during a plants reproductive stage, when plants are flowering, and helps make fruits and veggies hard and sweet, which can help prevent blossom end rot in tomatoes, for example. Methods of application: Similar to a simple superphosphate. Calcium phosphate stone crystals form when calcium atoms combine with phosphoric instead of oxalic acid and produce the calcium phosphate kidney stone. We’ll figure out a way to pull the calcium off the shell and get it to the plants. Note: this fires a little big, normally you would want to roast them a little slower, as you’re trying to avoid blackening them in favor of browning them a little. Put the crushed eggshells on the fire. Calcium phosphate is a family of materials and minerals containing calcium ions (Ca2+) together with inorganic phosphate anions. Your support is greatly appreciated! After you’ve added the vinegar – put a breathable cover over it (e.g., paper towel and rubber band) and store it in a cool dry place for 7-10 days. Natural farming says use whats around you so that’s what we tried. :), you’d use brown rice vinegar (BRV). We’re ready for the next step. Making Calcium Competent Cells Day 1 1. We also put a lot of good stuff in these beds, as the sign shows – some manure, compost and carbonized coos husks (i.e. love to try. Thanks for the tip. The heating process changes the shells; the burned ones will supply the calcium and the white ones will supply the phosphorus. I first learned about making WCA/WCP back in Hawaii and had good results using it there on tomatoes. When it comes to this combination of nutrients, your diet has a better chance of lacking the calcium, but you probably don't need to worry about phosphate. To get the calcium and calcium phosphate off the eggs and bones we use vinegar, which starts a reaction that releases the calcium, as well as carbon dioxide. Stephen. Work sterile. You’re welcome Alessandro :), thanks for checking in. Have great farming. The views and opinions expressed on this blog are mine and mine alone; as such, they do not reflect any position of the Peace Corps or the United States Government. Some so-called calcium phosphates contain oxide and … As a dietary supplement, it is commonly used as a source of calcium and phosphorus for both humans and animals. Thank you for reading and participating with my service in this way. They’re actually made from calcium phosphate. These beds were a small tribute to the island and the start of my quest to collect and share sugar cane juice with friends here. Normal total serum calcium is approximately 8.9–10.1 mg/dl (about 2.2–2.5 mmol/l). Heat the egg shells in the frying pan on medium heat until most of the shell pieces turn brown, even black with a little white. Now we have our browned eggshells and bones cooled and collected. If people knew it was sugar cane they would jump the fence and steal it to chew on. All the plants were sown at the same time and were the same size when we transferred them into these two beds. ( Log Out /  You can see that the bed on the right has clearly done better – growing both taller and a little greener during the few months. Your email address will not be published. I’ll explain it ‘Gambian style” below (i.e. Some so-called calcium phosphates contain oxide and hydroxide as well. We were really impressed with how well it worked, especially on this groundnut. Phosphoric acid is simply a phosphorus atom (shown as the ‘P’ in the line drawing to the left) with 4 oxygen atoms bonded to it. One thing we noticed was that almost immediately after adding WCA or WCP – the day after – we’d see 50-100 small weeds pop up. Don’t underestimate the power of this drink’s seemingly humble ingredients. Add acid phosphate and chocolate syrup to a tall glass. Original poster: Emmie from**. If someone is looking at you strangely, you know you are making it correctly and doing interesting things! Change ), You are commenting using your Google account. One option in the future would be to try to make our own vinegar, which would eliminate bringing another store bought item onto the farm and probably be more ‘natural,’ maybe with some better nutrients or vitamins in there that this vinegar doesn’t have. Calcium + Phosphorus = A Strong Combination . Save my name, email, and website in this browser for the next time I comment. Calcium can be bound to albumin and globulins. When the CaO at 573K is dissolved in H2O the hydrolyzing reaction  is so vigorous. Ok, so the mix is 1:10, by weight, eggshells to vinegar (e.g., 1oz eggshells mixed into 10oz vinegar). Calcium phosphate is a family of materials and minerals containing calcium ions (Ca 2+) together with inorganic phosphate anions. To use WCA/WCP dilute it 1:1000 (i.e. Sweet and salty. I searched all the day for eggshell/vinegar ratio and finally I have the answer: “mix is 1:10, by weight, eggshells to vinegar”. For the next part, you’ll need a frying pan. You can already see that the bed on the right, with the WCP applied, is a little taller. around a 1.25 tablespoon in 5 gallons of water). Day 2 1. If you can put that drum inside of a pot like a rotisserie, and the pot on coals, I bet you can toast them to the perfect shade of brown you want without a scorch on them. Feel free to comment or ask questions below. that is a very good information. If you’re here in Gambia with me that equates to about a 1/3 attaya glass in a standard 20L bidong. Add in 5 parts apple cider vinegar to the 1 part egg shell powder. Everyone knows you can easily add magnesium to your plants using either Epsom salt or molasses. Each sample used 0.25 g as-dried calcium phosphate powders that were uniaxially cold-pressed at 23 MPa to form a pellet with a diameter of 10 mm. They are white solids of nutritious value. He’s stabbing holes in it with his knife. Big thanks go out to my Hawaii farmer friends, especially ginger john, for teaching me about sugar cane and how to grow it, cut it, process it etc. Change ), You are commenting using your Facebook account. It worked for a little while :). This happened later on. Almost like the WCA/WCP woke them up. The composition contains (in small quantities): calcium sulfate, aluminum and iron phosphates and others. Just dose up the soil good then you can add various teas and such as/if needed during the grow. The fine powders were mechanically blended with 1 wt% PVA binder in a high-shear mill for 2 h and sieved after granulation. Throughout our spring blog series, we have shared how to propagate indigenous microorganisms, how to make fish amino acid, and how to make water soluble calcium for a thriving natural farming practice. Next, let the burned shells cool down before using a coffee grinder to turn the shells into a fine, dust-like powder. The water-soluble phosphorous (WCP) is sprayed on during vegetative growth phases of plants so they can produce a lot of “structure” like strong roots, stems, leaves etc. Upon oral uptake, calcium phosphate competes for and blocks the absorption of radium (Ra-226) and strontium in the gastrointestinal (GI) tract. After the 20 days, your calcium phosphate is ready to use. Fill in your details below or click an icon to log in: You are commenting using your account. Repeat after one week, if necessary. Eggshells carry lots of calcium carbonate but … Use the WCP first to get the plants structure going – apply to the leaves in the evening and watch the plants grow fast. Calcium phosphates are found in many living organisms, e.g., bone mineral and tooth enamel. It also takes more time to prepare than simply adding Epsom salt or molasses to your water. You can use DCP as a dietary supplement, an antacid and even a treatment for hypocalcemia, a calcium deficiency in the blood . Modou confirmed that it smelled bad and was weird: perfect! Today we will detail how to dissolve calcium phosphate in a water soluble solution using two simple ingredients: grass-fed beef bones and organic fermented vinegar. In this role, the compound is either used as an additive in the preparation of cereal and grain products or purchased as a meal supplement. Dicalcium phosphate (DCP) is a dibasic calcium phosphate formed by a reactive combination of calcium oxide and phosphoric acid. The purpose of this blog is to document my attempt to participate and help with the land: first as a Peace Corps Volunteer in the West African country of The Gambia and later on after my service is over on other farms in other places. Calcium phosphate can help thicken, stabilize and firm foods. Calcium Phosphate is the calcium salt of phosphoric acid with widely used applications. I will use, probably, apple vinegar. Good idea, yeah if we could get a rolling barrel or something going that would be nice. Write the date on the paper towel. Even the weeds we’re going wild in the WCA/WCP bed on the left. Don't just feed phosphate alone. Companies that make phosphoric acid in the U.S., Europe and elsewhere follow strict procedures to ensure purity. Making your own WSC is simple – extract the calcium from something you would normally be tossing – eggshells. WCA/WCP have the benefit of being water soluble, which allows the plant to quickly make use of it, as opposed to slower solid forms of Calcium and Phosphorous that can take longer to break down (e.g., crushed eggshells, limestone, etc.). First we’ll look at some sugar cane beds. Luckily, there are multiple types of calcium supplements, which usually come in the form of calcium salts. :), you’d use brown rice vinegar (BRV). Next up is our water-soluble calcium phosphate (WCP). First step is to get some old animal bones. Their results are said to be effective, but with improved method of production and correct usage, the benefits may be seen much faster. Fill the glass with ice to finish and serve with a straw. Add 2ml/L of water to create a foliar spray, solution to correct deficiencies, or as a regular part of your feeding schedule. You’ll want to place the jar into a sink for the next part because it will fizz considerably. Grow plate overnight at 37°C. A butcher may be a good spot, leftovers from steak night, or you can often buy bones from the supermarket. Drink 2 to 3 quarts of water a day to try and flush out the calcium phosphate deposits in your body. Introduced during digging in the fall or early spring, so that phosphorus has time to assimilate into the soil. Taller still. Once you make the calcium phosphate, you can add it to your water with either molasses or epsom salt to create CalMag+. Talk to your doctor before taking calcium phosphate if you are pregnant. Make sure to measure out the amount of shell powder before adding it to a jar. Food grade calcium phosphate acts … Drink lemon and orange juice. Calcium phosphate can dissolve slightly in the water containing CO2. In this post i’ll teach you how to make water-soluble calcium (WCA) and water-soluble calcium phosphate (WCP) then show you some of our results using it in the garden on sugar cane and groundnuts (i.e., peanuts). Change ). **Note: I didn’t make this recipe, I’m just sharing it to help my fellow growers! If you liked this post; Please like, comment or share! Luckily most people thought this was corn and didn’t steal it. This will take roughly 5-10 minutes to achieve. but if you’d like to see a more detailed write up you can check out the Hawaiian Natural Farming crew’s article at: Ok, let’s check out how we made and used WCA/WCP. Calcium phosphates are salts derived from phosphoric acid. Your bones need more than plain calcium. Food grade calcium phosphates primary function is to increase the calcium content of foods. If after 7 days there are no more bubbles its ready to use. Here is my other counterpart Modou with some WCA. These can include nutrient-containing runoff, which can cause problems in soils and plants. Ideally, and according to Natural Farming proper procedures, mandates, laws etc. Calcium phosphate is commonly found as a minor component of struvite and calcium oxalate uroliths. The photo below shows 2 beds: the one on the left was being given WCA/WCP at appropriate times and the one on the right wasn’t. Anecdotal accounts say that the citric acid in the juice will decrease the number of calcium phosphate kidney stones in the body. Like simple superphosphate, it is suitable for all types of soil and all plants. ( Log Out /  First step, get a fire going and gather your eggshells. 4 Cheap but Effective Ways to Increase Yields, Fermented Plant Juice to Boost Your Soils Microbial Life. Once the fizzing has mostly stopped, you can seal the jar up and ferment for 20 days. Just go to a plant nursery and get some dolomite limestone plus some organic bone meal and mix with your soil before you plant your seed, those should have all the cal/mag/phos your plant needs for cheap. Food forest part 4: It’s raining, plants are growing, we’re weeding and adding more compost. Phosphorus fertilizers include calcium phosphate derived from phosphate rock or bones. Before you get started, make sure your egg shells are thoroughly washed and the membrane inside is removed. The air contamination can make carbonate phase . Calcium phosphate co-precipitation has been a popular transfection method since its introduction in the early 1970s (Graham and van der Eb, 1973) because the components it requires are easily available and inexpensive. biochar). Sugar cane in Hawaiian is “Ko” which means “salt” in Mandinka. This photo is a week or so after we transferred them. We’ve got a lot of big tomato past cans here that would probably work for that. Ok, now lets see what WCA/WCP can do when applied to sugar cane and groundnut ( i’ll quit writing ‘peanut’ in parentheses now – you guys get it ). Calcium phosphate is used to make some chemical fertilizers. Good luck getting someones attaya glass to put this stuff in (it does look like attaya). Rinse the eggshells clean so there’s no more membrane or slime in there that could contaminate things. Enter your email address to subscribe to this blog and receive notifications of new posts by email. Once your shells are clean and dry, crush them up in your hands so they’re in small pieces. Calcium phosphate is insoluble in water, but soluble in acids: this property is used in Natural Farming. The eggshells will emit carbon dioxide so get ready for bubbles, a bad smell, and the mixture to possibly bubble out over the top. Ideally, and according to Natural Farming proper procedures, mandates, laws etc. In some cases, calcium phosphate is used in the production of fertilizers, although their overuse can cause adverse effects. It’s now bearing seed and received some WCA. At this point we were only applying WCP to help vegetative growth, as the flowers/reproductive stage had not come. The heating process changes the shells; the burned ones will supply the calcium and the white ones will supply the phosphorus. In Gambia we found a lot of goat and cow bones easily so decided to use them. Just go with it and think of all that great calcium going into the vinegar. Knowing that the soils here in Gambia can use all the help they can get, and that we have easy access to eggshells and animal bones, we thought we’d give this a shot. Eggshells, Bones and Vinegar – Water-Soluble Calcium and Calcium Phosphate (WCA / WCP), 2015 harvest, mini food forest and final welding project…. Calcium Phosphate Making Set Up. ©️ Copyright 2019-2020 Marijuana Mama 420, DIY Calcium Phosphate for creating DIY CalMag+. Tricalcium phosphate is one of these supplements. Both beds were identical except for the WCA/WCP with respect to initial plant size, sun, water, initial bed preparation (e.g., adding compost). Your body contains 1.2 to 2.5 pounds of calcium. Calcium and phosphate are present in bone in two basic structural forms which are utilized to buffer changes in extracellular calcium and phosphate concentrations on different timescales. For the next part, you’ll need a frying pan. Calcium phosphate biomaterials are well known in the medical materials and devices world, in particular, for their use in the treatment of osseous defects and as coatings on metal alloy prostheses and fixing devices. Let them dry overnight before continuing. Simply, filter the mixture into another jar for storage. This will take roughly 5-10 minutes to achieve. Try to get all the eggshells lightly roasted to a brown, not charring them into black carbon chunks.

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